版权所有@2014 《油气储运》杂志社 冀ICP备号:0000000
地址:河北省廊坊市金光道51号(065000);电话:0316-2177193 / 0316-2176753; 传真:0316-2177392; 网址:yqcy.paperonce.org
技术支持:西安三才科技实业有限公司 029-89381847;029-88222991
凝析气藏水合物抑制剂抑制性能协同效果
Synergistic effect of hydrate inhibitor for gas condensate reservoir
gas condensate reservoir
; hydrate; kinetic inhibitor; thermodynamic inhibitor; compounding effect凝析气藏采用加入水合物抑制剂的方法预防输送过程中水合物的生成,为了研究不同类型抑制剂的协同作用效果,基于对水合物热力学抑制剂与动力学抑制剂作用原理的分析,通过实验对动力学抑制剂(聚N-乙烯基吡咯烷酮)与热力学抑制剂(甲醇、乙二醇)的复合效果进行研究,重点研究了动力学抑制剂含量对醇体系抑制效果、不同醇含量体系对动力学抑制剂抑制效果的影响,选择性地实验了一定矿化度水对抑制效果的影响。结果表明:聚N-乙烯基吡咯烷酮与醇体系具有很好的配伍性,相互之间具有促进作用,二者复配可以有效提高抑制效果。
For a gas condensate reservoir, hydrate inhibitor is added to prevent the generation of hydrate in transportation. In order to study the synergistic effect of different inhibitors, the actions of thermodynamic and kinetic inhibitors are analyzed, and the composite effects of kinetic inhibitors (poly N-vinyl pyrrolidone) and thermodynamic inhibitors (methanol, ethylene glycol) are studied through experiments. Particularly, the effect of kinetic inhibitors on alcohol system and the impact of systems with different alcohol contents on the inhibitory effect are studied emphatically. The impact of certain salinity water on inhibitory effect is selectively tested. The results show that poly N-vinyl pyrrolidone is compatible with alcohol system, and they interact with each other and can be compounded to effectively improve the inhibitory effect.
[1]税碧垣. 管道天然气水合物的防治技术[J]. 油气储运, 2001, 20 (5) : 9-14.
SUI B H. The Prevention and elimination of natural gas hydrates in pipeline[J]. Oil and Gas Storage and Transportation, 2001, 20 (5) : 9-14.
[2]毕曼,贾增强,吴红钦,等. 天然气水合物抑制剂研究与应用进展[J].天然气工业, 2009, 29 (12) : 75-78.
BI M,JIA Z Q,WU H Q,et al. Update progress in research and application of natural gas hydrate inhibitor[J]. Natural Gas Industry, 2009, 29 (12) : 75-78.
[3]MAKOGON Y F,HOLDITCH S A,HOLSTE J C,et al. Aspects of gas hydrate kinetics[C]. Yokohama:Proceedings of the 4th International Conference on Gas Hydrates Yokohama Symposia,2002:531-536.
[4]刘海红,李玉星,王武昌,等. 天然气水合物颗粒间液桥力的理论研究[J].天然气工业, 2013, 33 (4) : 109-113.
LIU H H,LI Y X,WANG C W,et al. A theoretical study of liquid bridge force between natural gas hydrate particles[J]. Natural Gas Industry, 2013, 33 (4) : 109-113.
[5]梁德青,臧小亚,吴能友. 介观孔隙中天然气水合物生成过程模拟[J].天然气工业, 2013, 33 (7) : 24-28.
LIANG D Q,ZANG X Y,WU N Y. A simulation study of natural gas hydrate generation in mesoscopic-scale pores[J]. Natural Gas Industry, 2013, 33 (7) : 24-28.
[6]唐翠萍,樊栓狮.聚乙烯吡咯烷酮抑制水合物生成研究[J].天然气工业, 2006, 26 (3) : 125-128.
TANG C P,FAN S S. Research works about pvp inhibition performance on natural gas hydrate[J]. Natural Gas Industry, 2006, 26 (3) : 125-128.
[7]樊栓狮,王燕鸿,郎雪梅. 天然气水合物动力学抑制技术研究进展[J].天然气工业, 2011, 31 (12) : 99-109.
FAN S S,WANG Y H,LANG X M. Research progress of natural gas hydrate dynamic suppression techniques[J]. Natural Gas Industry, 2011, 31 (12) : 99-109.
[8]殷德宏,任亮,姚立忱,等. 天然气水合物生成动力学模型模拟计算改进[J].大连理工大学学报, 2004, 44 (4) : 486-489.
YIN D H,REN L,SHEN L Z,et al. Improved dynamic model imitation calculations for natural gas hydrate formation[J]. Journal of Dalian University Of Technology, 2004, 44 (4) : 486-489.
[9]陈赓良. 天然气采输过程中水合物的形成与防止[J]. 天然气工业, 2004, 24 (8) : 89-91.
CHEN G L. Formation and prevention of hydrate during process of gas exploitation and transmission[J]. Natural Gas Industry, 2004, 24 (8) : 89-91.
[1]李玉星,朱超,王武昌,等.天然气水合物浆液稳定性影响因素的正交实验[J].油气储运,2011,30(09):685.[doi:10.6047/j.issn.1000-8241.2011.09.011]
Li Yuxing,Zhu Chao,Wang Wuchang,et al.Orthogonal-experimental research on stability effecting factors of hydrate slurry[J].Oil & Gas Storage and Transportation,2011,30(10):685.[doi:10.6047/j.issn.1000-8241.2011.09.011]
[2]李大全 艾慕阳 王玉彬 苗青 赵国辉 刘凯.涩宁兰输气管道水合物事故及其预防[J].油气储运,2012,31(4):267.[doi:10.6047/j.issn.1000-8241.2012.04.007]
Li Daquan,Ai Muyang,Wang Yubin,et al.Hydrate accident and prevention in Sebei-Xining-Lanzhou Gas Pipeline[J].Oil & Gas Storage and Transportation,2012,31(10):267.[doi:10.6047/j.issn.1000-8241.2012.04.007]
[3]宋琦,王树立,武雪红,等.水合物技术应用与展望[J].油气储运,2009,28(9):5.[doi:10.6047/j.issn.1000-8241.2009.09.002]
SONG Qi,WANG Shuli.Application and Prospect of Natural Gas Hydrate Technology[J].Oil & Gas Storage and Transportation,2009,28(10):5.[doi:10.6047/j.issn.1000-8241.2009.09.002]
[4]王卫强,吴明,王勇,等.天然气水合物的制备和存储[J].油气储运,2007,26(1):1.[doi:10.6047/j.issn.1000-8241.2007.01.001]
WANG Weiqiang,WU Ming.The Preparation and Storage of Natural Gas Hydrate[J].Oil & Gas Storage and Transportation,2007,26(10):1.[doi:10.6047/j.issn.1000-8241.2007.01.001]
[5]宋磊,钱旭,吴敏,等.天然气水合物的储存和运输可行性研究[J].油气储运,2005,24(3):9.[doi:10.6047/j.issn.1000-8241.2005.03.003]
SONG Lei,QIAN Xu.Feasibility of Storage and Transportation of Gas Hydrate[J].Oil & Gas Storage and Transportation,2005,24(10):9.[doi:10.6047/j.issn.1000-8241.2005.03.003]
[6]孙志高,郭开华,樊栓狮.气体水合物储存甲烷促进技术研究[J].油气储运,2004,23(6):45.[doi:DOI:10.6047/j.issn.1000-8241.2004.06.014]
SUN Zhigao,GUO Kaihua.Study on Promotion Technology of Methane Storage in Hydrate[J].Oil & Gas Storage and Transportation,2004,23(10):45.[doi:DOI:10.6047/j.issn.1000-8241.2004.06.014]
[7]孔昭瑞.天然气非常规储运技术及其发展前景[J].油气储运,2003,22(7):1.[doi:DOI:10.6047/j.issn.1000-8241.2003.07.001]
KONG Zhaorui.Unconventional Storage and Transportation Technology of Gas and its Prospects[J].Oil & Gas Storage and Transportation,2003,22(10):1.[doi:DOI:10.6047/j.issn.1000-8241.2003.07.001]
[8]邓实,包成林,张惠芬,等.天然气测试研究的现状及建立实验室的必要性[J].油气储运,2002,21(3):49.[doi:10.6047/j.issn.1000-8241.2002.03.015]
DENG Shi,BAO Chenglin.The Status Quo of Gas Measurement & Research and Necessity to Establish Natural Gas Laboratory[J].Oil & Gas Storage and Transportation,2002,21(10):49.[doi:10.6047/j.issn.1000-8241.2002.03.015]
[9]喻西崇,赵金洲,郭建春,等.天然气水合物生成条件预测模型的比较[J].油气储运,2002,21(1):20.[doi:DOI:10.6047/j.issn.1000-8241.2002.01.006]
YU Xichong,ZHAO Sinzhou.The Prediction Model Comparison of Gas Hydrate Formation Conditions[J].Oil & Gas Storage and Transportation,2002,21(10):20.[doi:DOI:10.6047/j.issn.1000-8241.2002.01.006]
[10]杨峋,李玉星.利用水合物实现天然气的固态输送[J].油气储运,2000,19(10):5.[doi:10.6047/j.issn.1000-8241.2000.10.002]
Yang Xun,Li Yuxing.A New Way of Gas Transportation——Solid-state Transportation of Natural Gas in the Form of Hydrates,[J].Oil & Gas Storage and Transportation,2000,19(10):5.[doi:10.6047/j.issn.1000-8241.2000.10.002]
收稿日期:2013-7-18;改回日期:2014-4-17。
作者简介:张吉红,在读硕士生,1983年生,2008 年毕业于西南石油大学化学工程与工艺专业,现主要从事化学品管理、天然气管网腐蚀与防护技术研究。E-mail:zjh12@mails.tsinghua.edu.cn